Tech graduate students tackle problem of heavy metals in Tennessee greens - News

Tech graduate students tackle problem of heavy metals in Tennessee greens

Tech students recently researched pulling heavy metal deposits out of leafy greens.
Tech students recently researched pulling heavy metal deposits out of leafy greens.


Three Tennessee Tech University graduate students recently developed a project to take a closer look at an important issue facing local farms: the presence of heavy metals like mercury and cadmium in the soil. These toxic metals can be transferred from the ground into spinach and other leafy greens, posing a health risk to consumers.

“Leafy greens take up heavy metals at higher rates, particularly into the part of the plant that you eat,” explained Ronnie Dunn, doctoral student in environmental science. “So, we asked the questions: can heavy metals be reduced in soils? Is it possible that we could maybe limit the uptake of heavy metals in a plant like spinach? Or is it possible we can do both?”

He and his fellow students, Shafieh Karami, a doctoral student in chemical engineering, and Kitty Philips, a doctoral student in environmental science, interviewed three local farmers to learn more about this challenge.

“All three were in agreement regarding our concerns about the heavy metals and especially uptake in the vegetables that they're growing,” Philips said.

According to the students’ research on established studies on heavy metals in the soils in the United States, unsafe levels of mercury and cadmium are not uncommon in Tennessee.

“The USDA (United States Department of Agriculture) every so often takes food samples from the market and 93 percent of food samples had cadmium in it. Spinach, in that same study, was sometimes twice the WHO (World Health Organization) recommended limit, which is a bit scary,” Dunn said.

“Both cadmium and mercury exposure could cause very severe illnesses like kidney damage, lung damage, skin irritation, retinal damage and bone damage,” added Karami, “And also, being exposed to these two metals can raise our chances to develop cancer later on in life.”

Dunn, Karami and Philips are trainees in a National Research Traineeship program established at Tech in 2022 from a $3 million grant from the National Science Foundation for the project entitled “Engendering the Spirit of Gadugi at the Food-Energy-Water Nexus.”  Currently, the program has graduate students enrolled across several doctoral and master’s degree programs highlighting the interdisciplinary nature of the efforts.

One of the project’s goals is to empower graduate students to identify and work collaboratively with internal and external partners to solve challenges involving food, energy and/or water with a particular emphasis in working with those in Appalachian, other rural and Cherokee communities in Tennessee.

This approach is guided by a strong sense of community-based partnerships and transformation, says Andrea Arce-Trigatti, faculty in the department of Curriculum and Instruction and a member of the Renaissance Foundry Research Group at Tech.

To engage with investigating the heavy metals in soils challenge, the student team used the Renaissance Foundry Model, an effort led by Pedro E.  Arce, professor of chemical engineering at Tech, and his colleagues, J. Robby Sanders and Arce-Trigatti, which emphasizes innovation-driven efforts guided by critical thinking, leadership and team-based skills. They also received training in critical thinking and community-based collaborations from Sabrina Buer, the TTU-NRT program coordinator; Troy Smith, professor of History; Ada Haynes, professor of sociology and political science; and Rufaro Chitiyo, associate professor of human ecology.

As part of this process, the student team developed a two-step approach to help alleviate some of the problem. In their research, they found that the plant called “prince’s feather” can remove up to two-thirds of these metals from the surrounding soil when the soil’s pH is low. The solution’s first step would be, during the spring and early summer, lowering the soil’s pH and planting these prince’s feathers in the spot where the farmers will later plant leafy greens in late summer and fall, which could potentially remove a large portion of the contaminants.

Prince’s feather grows best in Tennessee in the spring/early summer, so in the late summer and fall, farmers could add biochar and lime, soil amendments which make heavy metals less able to be absorbed by the leafy greens. The student’s model showed this approach could significantly reduce the levels of heavy metals remaining in the soil and in turn, the spinach crops.

“Also, if you're really industrious, you can sell the (prince’s feather) flowers to the floral industry. They're pretty popular,” said Philips.

To make their solution accessible for home gardeners, the team designed a "Safe Spinach" product prototype: a box containing all the materials needed to implement their remediation approach in a 4x8 foot garden bed, such as pH tests, organic fertilizers, spinach seeds and compounds to raise and lower the soil pH. The box and packaging would be made from compostable materials as well. They estimated that the box could cost around $60 from a commercial retailer and would produce around 16 pounds of spinach on one cutting, as well as the flowers.

“That’s $3.73 a pound, whereas [a major retailer's] organic spinach is $9.54 a pound and that might have some heavy metals in it,” Dunn said.

The student team presented their work to a community-led group of judges at the end of the semester and followed up with their community partners as part of the course’s learning outcomes.

“This is important feedback from experts and community partners that calibrates the student team’s efforts,” said Arce.

“The TTU-NRT program guides students through core and elective courses and a host of other experiential activities, progressively pursued, to facilitate the acquisition of knowledge relevant to the three key components of the program, i.e., community-centered problem identification and solution development (centered on the Foundry), critical thinking skills (centered on the Critical thinking Assessment Test, CAT) and community relevant communication skills (centered on the three key partnering communities: Cherokee, Appalachian and other rural populations including Hispanic/Latino, African American and others),” said Sanders.